The order of the columns in a table in a Power BI dataset doesn’t matter all that much, especially because the Fields pane in Power BI Desktop ignores the original column order and lists the columns in a table in alphabetical order. However there are a few situations where it is important, for example when you are using the DAX Union() function in a calculated table: as the documentation states, when you use Union() “Columns are combined by position in their respective tables”. You might also find it irritating if the columns you see in the Data or Relationships panes in the main Power BI Desktop window make it hard to browse the data or create relationships.